Product ID:SANODAL DEEP BLACK H3LW PASTE, 1-0491-2-100
MSDS Date:02/02/1988
FSC:8030
NIIN:00N022455
MSDS Number: BLYBH

SANDOZ CHEMICALS

4000 MONROE RD
CHARLOTTE, NC 28205
US

Emergency Phone: 704-827-9651;800-424-9300(CHEMTREC)

Info Phone: 704-827-9651

Cage: 1Y044

CLARIANT CORP

CHARLOTTE, NC 28205 US

Telephone: 908-429-3562

Cage: 1Y044

CHROMIUM

CAS: 7440-47-3

RTECS: GB4200000

Fraction By Weight: 1-2%

OSHA PEL 1 MG(CR)/M3

ACGIH TLV: 0.5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

FORMIC ACID

CAS: 64-18-6

RTECS: LQ4900000

Fraction By Weight: 0.5-1.0%

OSHA PEL 5 PPM

ACGIH TLV: 5 PPM;10 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2,4-PENTANEDIOL, 2-METHYL-; (HEXYLENE GLYCOL)

CAS: 107-41-5

RTECS: SA0810000

Fraction By Weight: 1-3%

OSHA PEL 25 PPM, C

ACGIH TLV: 25 PPM, C

LD50 LC50 Mixture:LD50:ORAL(RAT)>2000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHROMIUM:CHROMIUM & CERTAIN COMPOUNDS
OF CHROMIUM HAVE BEEN REPORTED TO CAUSE DAMAGE TO LUNGS RESULTING
IN CUMULATIVE DAMAGE TO LUNGS & FROM RESULTS OF TESTING WITH LAB
ANIMALS ARE SUSPECTED OF CAUSIN G CANCER. DERMATITIS HAS BEEN
REPORTED FROM RPTD/PRLNG CONTACT WITH CHROMIUM COMPOUNDS. SENSIT
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM:IARC GROUP (1);NTP GROUP 1.
Effects of Overexposure:HLTH HAZ: MAY OCCUR ON RPTD CONTACT. THERE HAVE
BEEN NO REPORTS OF ANY OF THESE EFFECTS FROM THE USE OF THIS
PRODUCT. FORMIC ACID IS CORROSIVE TO SKIN AND EYES. HEXYLENE GLYCOL
MAY IRRITATE EYES, SKIN , AND RESPIRATORY TRACT. PRLNG/RPTD
EXPOSURE TO SKIN WILL DEGREASE SKIN. NO KNOWN EFTS OR OTHER
ILLNESSES FOR PRODUCT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: WASH THOROUGHLY WITH SOAP AND WATER FOR 15 MIN. IF
IRRITATION OCCURS, SEEK MED ATTN. EYES: FLUSH IMMED UNDER RUNNING
WATER FOR AT LEAST 15 MIN. IF REDNESS OR IRRITATION OCCURS, SEEK
MED ATTN. IN HAL: GET VICTIM TO FRESH AIR. GIVE ARTFRESP/O*2 IF
BREATHING HAS STOPPED. GET PROMPT MED ATTN. DO NOT GIVE FLUIDS IF
VICTIM IS UNCON. INGEST: SEEK MED ASSISTANCE.

Extinguishing Media:WATER, ALCOHOL FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. PVNT
RUNOFF TO SEWERS & BODIES OF H*2O FROM FIRE FIGHT INVOLVING PROD AS
PROD CNTNS CLEAN H*2O ACT (SUPDAT)
Unusual Fire/Explosion Hazard:NONE KNOWN.

Spill Release Procedures:CNTN SPILL. CNTN HEAVY METALS. AVOID RUNOFF TO
SEWERS & BODIES OF H*2O. WEAR PROPER PROT EQUIP. ABSORB ON SUITABLE
ABSORB MATL. CLEAN UP BY SCRUBBING WITH SOAP & H*2O. COLLECT
CLEANING WASTES, OR REMO VE CONTAMINATED SOILS. PLACE IN PROPER
CONTR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED. AVOID GETTING
ON SKIN OR IN EYES WHEN HANDLING PRODUCT.
Other Precautions:IN ACCORDANCE WITH GOOD PRACTICES OF PERSONAL
CLEANLINESS-HYGIENE, HANDLE WITH DUE CARE AND AVOID ANY UNNECESSARY
CONTACT WITH THIS PRODUCT.

Respiratory Protection:NONE REQUIRED IN NORMAL USE OF PRODUCT. USE
NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN
.
Ventilation:LOCAL VENTILATION RECOMMENDED-MECHANICAL VENTILATION MAY BE
USED.
Protective Gloves:BUTYL RUBBER, PVC OR NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:PRIORITY POLLUTANTS AND WILL ALSO BE A RCRA HAZ WASTE
MATL.

pH:SUPDAT
Solubility in Water:20 G/L@60
Appearance and Odor:BLACK PASTE, NO ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
OXIDES OF CARBON, NITROGEN, AND SULFUR. ASH WILL CONTAIN CHROMIUM.

Waste Disposal Methods:PROD BECOMES RCRA HAZ WHEN IT BECOMES WASTE MATL
DUE TO CHROMIUM CONTENT. RECOM DISP IS BY INCINERATION W/PROPER AIR
SCRUBBING DEVICES @ APPRVD FACILITIES. MAY ALSO BE LANDFILLED IN
APPROVED FACILITIE S. DISPOSE OF I/A/W FED, ST, & LOC REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.